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PAPER
Tuning of aluminum concentration distribution in high nickel cathode particles for lithium ion batteries관리자2020-05-12 조회 1,976 댓글 0이메일주소 site@site.co.kr Author Ilbok Lee, Joongho Bae, Jaekwang Kim, Young-Min Kim, Don-Hyung Ha, Hyungbin Son, Songhun Yoon Journal Journal of Alloys and Compounds Year of Pub. 2020
This study focuses on a novel approach for the structural design of LiNi0.86Co0.12Al0.02O2 cathodes by tailoring the distribution of Al elements using milled-Al(OH)3. The distribution of Al in the cathode material is investigated using an electron probe micro analyzer. By controlling milled-Al(OH)3 addition time at 3 and 6 h, thickness of Al-rich layer is varied during co-precipitation process and following calcination with LiOH produces cathode materials with the variant Al distribution. Initial discharge capacities of the cathodes with the Al addition at 3 and 6 h are 202 and 195 mA h g−1 and the IE (initial efficiency) is 92.5 and 86.6%, respectively. The capacity retentions from the cycling test of the individual cathodes are as high as 96.7 and 92.6% at 50 cycles under 1 C rate, respectively. This advanced electrochemical performance is attributed to gradual increase of Al element from inner to outer in active material.
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