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    In situ Zr incorporation during co-precipitation regulates dopant distribution and crystallographic texture in Ni-rich layered cathodes
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    2026-10-03      조회 0   댓글 0  
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    Author Jaegyun Heo, Taejun Koh, Yeon-su Kim, Daiha Shin, Jinyeong Kim, Soeun Jo, Jiung Cho, Songhun Yoon a
    Journal Chemical Engineering Journal
    Year of Pub. 2026


    In this study, we demonstrate that the Zr incorporation route governs not only dopant distribution but also precursor crystallographic growth and cathode texture development in Ni-rich layered cathodes. Comprehensive physicochemical characterization revealed that the precursor-stage, in situ Zr-incorporated cathode (NCMZr-c) exhibited a homogeneous Zr distribution throughout the secondary particles and a distinct crystallographic texture favored by precursor-stage Zr-mediated growth regulation, in contrast to the post-solid-state Zr-incorporated cathode (NCMZr-p). These features synergistically mitigated anisotropic lattice contraction, alleviated localized strain accumulation, and preserved lithium-ion transport kinetics during repeated high-voltage cycling up to 4.5 V. Consequently, NCMZr-c retained 96.7% and 86.4% of its initial capacity after 100 cycles at 4.3 and 4.5 V, respectively, at a 1C rate. Post-cycling transmission electron microscopy revealed a markedly thinner rocksalt-like surface layer for NCMZr-c (~3 nm) than for pristine NCM (~13 nm), together with substantially suppressed intergranular cracking. This study establishes precursor-stage Zr incorporation as an effective approach for coupling dopant distribution control with crystallographic texture regulation, providing a useful insight into designing doping strategies to enhance the structural stability of Ni-rich layered oxide cathodes. 

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